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Sesquicarbene Complexes: Bonding at the Interface Between M–C Single Bonds and M═C Double Bonds

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Allylic dimetalated complexes [M2C(vinyl)]+ (M = Au(IPr) and Cr(CO)5–) incorporate a new coordination mode of carbon. Digold complexes of this type have recently been detected experimentally. The i... Click to show full abstract

Allylic dimetalated complexes [M2C(vinyl)]+ (M = Au(IPr) and Cr(CO)5–) incorporate a new coordination mode of carbon. Digold complexes of this type have recently been detected experimentally. The i...

Keywords: interface single; bonding interface; single bonds; bonds double; complexes bonding; sesquicarbene complexes

Journal Title: Organometallics
Year Published: 2020

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