"Evidence for Silica Surface Three- and Five-Membered Metallacycle Intermediates in the Catalytic Cycle of Hydroaminoalkylation of Olefins Using Single-Ti-Metal Catalysts"

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Evidence for Silica Surface Three- and Five-Membered Metallacycle Intermediates in the Catalytic Cycle of Hydroaminoalkylation of Olefins Using Single-Ti-Metal Catalysts

The single-site silica-supported group IV metal amido complex [Ti(NMe2)4] gives the tris(amido)-supported fragment [(≡Si–O−)Ti(−NMe2)3], which transforms into a three-membered metallacycle (called ... Click to show full abstract

Keywords: surface three; membered metallacycle; evidence silica; metal; silica surface

Journal Title: Organometallics
Year Published: 2020

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