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Transformation of Thiolatogold(I) to an Au Complex with an (Arylthio)silyl Ligand. Use of an (Aminosilyl)boronic Ester as a Silylene Precursor

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The gold(I) thiolate complex [Au(SC6H4-4-OMe)(PCy3)] reacts with an (aminosilyl)boronic ester, Et2N-SiPh2-BO(CMe2)2O, to afford a complex with an (arylthio)silyl ligand, [Au(SiPh2(SC6H4-4-OMe))(PCy... Click to show full abstract

The gold(I) thiolate complex [Au(SC6H4-4-OMe)(PCy3)] reacts with an (aminosilyl)boronic ester, Et2N-SiPh2-BO(CMe2)2O, to afford a complex with an (arylthio)silyl ligand, [Au(SiPh2(SC6H4-4-OMe))(PCy...

Keywords: silyl ligand; aminosilyl boronic; boronic ester; arylthio silyl; complex arylthio

Journal Title: Organometallics
Year Published: 2020

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