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Controlling P–C/C–H Bond Cleavage in Nickel Bis(diphosphine) Complexes: Reactivity Scope, Mechanism, and Computations

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The synthesis of heteroleptic [Ni(P2N2)(diphosphine)][BF4]2 complexes and the cleavage of P–C and C–H bonds of the P2N2 ligand in those complexes are reported. The products are five-coordinate comp... Click to show full abstract

The synthesis of heteroleptic [Ni(P2N2)(diphosphine)][BF4]2 complexes and the cleavage of P–C and C–H bonds of the P2N2 ligand in those complexes are reported. The products are five-coordinate comp...

Keywords: cleavage nickel; nickel bis; cleavage; controlling bond; bond cleavage; diphosphine

Journal Title: Organometallics
Year Published: 2020

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