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Synthesis, Reactivity, and Insights into the Lewis Acidity of Mononuclear Titanocene Imido Complexes Bearing Sterically Demanding Terphenyl Moieties

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The titanocene imido complex 2 with a m-terphenyl moiety is synthesized by reacting Cp2Ti(η2-Me3SiC2SiMe3) (1) with m-terphenyl azide. Subsequent reactivity studies with tetrahydrofuran, pyridine, ... Click to show full abstract

The titanocene imido complex 2 with a m-terphenyl moiety is synthesized by reacting Cp2Ti(η2-Me3SiC2SiMe3) (1) with m-terphenyl azide. Subsequent reactivity studies with tetrahydrofuran, pyridine, ...

Keywords: imido; insights lewis; reactivity insights; synthesis reactivity; titanocene imido

Journal Title: Organometallics
Year Published: 2020

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