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Coordination-Induced N–H Bond Weakening in a Molybdenum Pyrrolidine Complex: Isotopic Labeling Provides Insight into the Pathway for H2 Evolution

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The synthesis and characterization of a cationic molybdenum pyrrolidine complex are described that exhibits significant coordination-induced N–H bond weakening. The N–H bond dissociation free energ... Click to show full abstract

The synthesis and characterization of a cationic molybdenum pyrrolidine complex are described that exhibits significant coordination-induced N–H bond weakening. The N–H bond dissociation free energ...

Keywords: pyrrolidine complex; induced bond; bond; molybdenum pyrrolidine; bond weakening; coordination induced

Journal Title: Organometallics
Year Published: 2020

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