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Bridged and Unbridged Nickel–Nickel Bonds Supported by Cyclopentadienyl and Phosphine Ligand Sets

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A series of Ni complexes [Ni(Cl)2(PR3)2] with R = Me (1-Me), nPr (1-nPr), and nBu (1-nBu) and nickelocenes [Ni(η5-C5H4R′)2] with R′ = H (2-H), Me (2-Me), and SiMe3 (2-SiMe3) were… Click to show full abstract

A series of Ni complexes [Ni(Cl)2(PR3)2] with R = Me (1-Me), nPr (1-nPr), and nBu (1-nBu) and nickelocenes [Ni(η5-C5H4R′)2] with R′ = H (2-H), Me (2-Me), and SiMe3 (2-SiMe3) were synthesized and ch...

Keywords: bridged unbridged; unbridged nickel; bonds supported; supported cyclopentadienyl; nickel bonds; nickel nickel

Journal Title: Organometallics
Year Published: 2020

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