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Bis(tetramethylaluminate) Lanthanide Complexes Supported by Bi- and Tridentate Amidinate Ligands: Performance in Isoprene Polymerization

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The isolable bis(tetramethylaluminate) lanthanide complexes [2-R2,6-XC6H4NC(tBu)(2,6-R12C6H3)]Ln(AlMe4)2 (R1 = R2 = X = Me, Ln = La (1); R1 = R2 = X = Me, Ln = Nd (2); R1 =… Click to show full abstract

The isolable bis(tetramethylaluminate) lanthanide complexes [2-R2,6-XC6H4NC(tBu)(2,6-R12C6H3)]Ln(AlMe4)2 (R1 = R2 = X = Me, Ln = La (1); R1 = R2 = X = Me, Ln = Nd (2); R1 = iPr, R2 = H, X = OMe, Ln...

Keywords: supported tridentate; complexes supported; lanthanide complexes; bis tetramethylaluminate; tetramethylaluminate lanthanide

Journal Title: Organometallics
Year Published: 2021

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