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Isolation of a [Fe(CO)4]2–-Bridged Diuranium Complex Obtained via Reduction of Fe(CO)5 with Uranium(III)

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Treatment of the U(III) complex, [(C5Me5)2U(OMes)(THF)], Mes = 2,4,6-Me3C6H2, with Fe(CO)5 forms [{(C5Me5)2(MesO)U}2(μ2-(OC)2Fe(CO)2)] with the bridging, tetrahedral Fe(CO)4 moiety. This complex ha... Click to show full abstract

Treatment of the U(III) complex, [(C5Me5)2U(OMes)(THF)], Mes = 2,4,6-Me3C6H2, with Fe(CO)5 forms [{(C5Me5)2(MesO)U}2(μ2-(OC)2Fe(CO)2)] with the bridging, tetrahedral Fe(CO)4 moiety. This complex ha...

Keywords: iii; complex obtained; isolation bridged; diuranium complex; bridged diuranium; obtained via

Journal Title: Organometallics
Year Published: 2021

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