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Diastereoselective Synthesis of Planar Chiral Phosphoramidites with a Ferrocenophane Scaffold

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A new family of planar chiral phosphoramidites with a [3]ferrocenophane structure was synthesized. The synthetic strategy involved diastereoselective formation of the chiral ferrocene units from suitable substituted bis-cyclopentadienyl derivatives. Preliminary… Click to show full abstract

A new family of planar chiral phosphoramidites with a [3]ferrocenophane structure was synthesized. The synthetic strategy involved diastereoselective formation of the chiral ferrocene units from suitable substituted bis-cyclopentadienyl derivatives. Preliminary coordination studies of these ligands were undertaken with the synthesis of palladium and platinum complexes.

Keywords: phosphoramidites ferrocenophane; diastereoselective synthesis; chiral phosphoramidites; synthesis planar; planar chiral

Journal Title: Organometallics
Year Published: 2017

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