A new family of planar chiral phosphoramidites with a [3]ferrocenophane structure was synthesized. The synthetic strategy involved diastereoselective formation of the chiral ferrocene units from suitable substituted bis-cyclopentadienyl derivatives. Preliminary… Click to show full abstract
A new family of planar chiral phosphoramidites with a [3]ferrocenophane structure was synthesized. The synthetic strategy involved diastereoselective formation of the chiral ferrocene units from suitable substituted bis-cyclopentadienyl derivatives. Preliminary coordination studies of these ligands were undertaken with the synthesis of palladium and platinum complexes.
               
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