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Hafnium(II) Complexes with Cyclic (Alkyl)(amino)carbene Ligation

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The formal hafnium(II) complexes with cyclic (alkyl)(amino)carbene (cAAC) ligation [(Me2-cAAC)2HfCl2] and [(Me2-cAAC)2Hf(CH2Ph)2] (Me2-cAAC = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidine-2-ylidene) have been synthesized and structurally characterized. Click to show full abstract

The formal hafnium(II) complexes with cyclic (alkyl)(amino)carbene (cAAC) ligation [(Me2-cAAC)2HfCl2] and [(Me2-cAAC)2Hf(CH2Ph)2] (Me2-cAAC = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidine-2-ylidene) have been synthesized and structurally characterized.

Keywords: amino carbene; complexes cyclic; hafnium complexes; alkyl amino; cyclic alkyl

Journal Title: Organometallics
Year Published: 2018

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