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Resting/dormant benzyl- and allyl-type Ti(IV) complexes formed under α-olefin polymerization conditions have been detected and characterized by NMR. Experimental and computational evidence supports a formation mechanism via reversible Ti–C bond… Click to show full abstract
Resting/dormant benzyl- and allyl-type Ti(IV) complexes formed under α-olefin polymerization conditions have been detected and characterized by NMR. Experimental and computational evidence supports a formation mechanism via reversible Ti–C bond homolysis rather than “classical” σ-bond metathesis.
Keywords:
mechanism;
toluene olefins;
evidence;
allyl;
radical scavengers;
olefins radical
Journal Title: Organometallics
Year Published: 2018
Link to full text (if available)
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Journal Title: Organometallics
Year Published: 2018
Link to full text (if available)
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recommendations!