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Formation of an α-Diimine from Isocyanide Coupling Using Thorium(IV) and Uranium(IV) Phosphido–Methyl Complexes

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To probe the reactivity of two potential sites at tetravalent thorium and uranium metal centers, we examined the monophosphido methyl complexes, (C5Me5)2An(CH3)[P(SiMe3)(Mes)], An = Th, U; Mes = 2,... Click to show full abstract

To probe the reactivity of two potential sites at tetravalent thorium and uranium metal centers, we examined the monophosphido methyl complexes, (C5Me5)2An(CH3)[P(SiMe3)(Mes)], An = Th, U; Mes = 2,...

Keywords: isocyanide coupling; formation diimine; diimine isocyanide; thorium uranium; methyl complexes

Journal Title: Organometallics
Year Published: 2019

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