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Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cyclic… Click to show full abstract
Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cyclic allyl products and is compatible with heterocyclic allyl chloride electrophiles.
Keywords:
allyl;
hiyama cross;
highly enantioselective;
enantioselective hiyama;
cross coupling;
racemic allyl
Journal Title: Organometallics
Year Published: 2019
Link to full text (if available)
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Journal Title: Organometallics
Year Published: 2019
Link to full text (if available)
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recommendations!