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We report the preparation of enantioenriched secondary alkylcarbastannatranes via a stereoinvertive SN2 reaction of enantioenriched alkyl mesylates and carbastannatranyl anion equivalents. Using this process, enantioenriched secondary alcohols may be converted… Click to show full abstract
We report the preparation of enantioenriched secondary alkylcarbastannatranes via a stereoinvertive SN2 reaction of enantioenriched alkyl mesylates and carbastannatranyl anion equivalents. Using this process, enantioenriched secondary alcohols may be converted into highly enantioenriched alkylcarbastannatranes, which are useful in stereospecific cross-coupling reactions.
Keywords:
alkyl mesylates;
enantioenriched alkylcarbastannatranes;
stereospecific cross;
alkylcarbastannatranes via;
cross coupling;
preparation enantioenriched
Journal Title: Organometallics
Year Published: 2019
Link to full text (if available)
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Journal Title: Organometallics
Year Published: 2019
Link to full text (if available)
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recommendations!