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Parent Cyclopentadienyl Ruthenium(II) Chloride Synthon: Derivatization to CpRu Amido, Imido, and Oxo Complexes

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The complex salt [CpRu(η6-C10H8)][(CpRu)2(μ-Cl)3] ([1][2]) was synthesized and found to be a useful CpRuCl synthon. The ions [1]+ and [2]− cleanly comproportionate into monomeric CpRuCl(L)2 complex... Click to show full abstract

The complex salt [CpRu(η6-C10H8)][(CpRu)2(μ-Cl)3] ([1][2]) was synthesized and found to be a useful CpRuCl synthon. The ions [1]+ and [2]− cleanly comproportionate into monomeric CpRuCl(L)2 complex...

Keywords: ruthenium chloride; synthon; chloride synthon; parent cyclopentadienyl; cpru; cyclopentadienyl ruthenium

Journal Title: Organometallics
Year Published: 2019

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