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Reactivity of Aluminum Complexes of Redox-Active Ligand toward N-Heterocyclic Carbene and Its Thione

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The reaction of dialane (dpp-Bian)Al–Al(dpp-Bian) (1) (dpp-Bian is dianion of 1,2-bis[(2,6-diisopropylphenyl)imino]-acenaphthene) with 1 mol equiv of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene ... Click to show full abstract

The reaction of dialane (dpp-Bian)Al–Al(dpp-Bian) (1) (dpp-Bian is dianion of 1,2-bis[(2,6-diisopropylphenyl)imino]-acenaphthene) with 1 mol equiv of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene ...

Keywords: reactivity aluminum; active ligand; complexes redox; dpp bian; redox active; aluminum complexes

Journal Title: Organometallics
Year Published: 2019

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