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Diffusion NMR Studies on the Self-Aggregation of Ru-Arene CAP Complexes: Evidence for the Formation of H-Bonded Dicationic Species in Acetonitrile

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The self-aggregation of neutral [RuCl2(η6-p-cymene)(CAP)] (2; p-cymene = 1-methyl-4-(propan-2-yl)benzene) and ionic [RuCl(η6-p-cymene)(L)(CAP)](PF6) (3, L = CAP; 4, L = MeCN) and [RuCl2(η6-p-cymene... Click to show full abstract

The self-aggregation of neutral [RuCl2(η6-p-cymene)(CAP)] (2; p-cymene = 1-methyl-4-(propan-2-yl)benzene) and ionic [RuCl(η6-p-cymene)(L)(CAP)](PF6) (3, L = CAP; 4, L = MeCN) and [RuCl2(η6-p-cymene...

Keywords: nmr studies; self aggregation; cymene; diffusion nmr; cap

Journal Title: Organometallics
Year Published: 2019

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