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Host-Guest Complexation of Perethylated Pillar[6]arene toward Ferrocene Derivatives Both in Solution and Solid State: Different Binding Modes Induced by Minor Structural Changes of Guests.

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Herein, novel host-guest properties between perethylated pillar[6]arene and four kinds of ferrocene derivatives were fully investigated. NMR titrations, 2D NOESY NMR spectroscopy, and ESI-MS are used to confirm that they… Click to show full abstract

Herein, novel host-guest properties between perethylated pillar[6]arene and four kinds of ferrocene derivatives were fully investigated. NMR titrations, 2D NOESY NMR spectroscopy, and ESI-MS are used to confirm that they indeed formed stable inclusion complexes. Two precious single-crystal structures were obtained and showed that ferrocene derivatives with different chemical structures exhibit different binding modes with perethylated pillar[6]arenes.

Keywords: perethylated pillar; binding modes; ferrocene derivatives; host guest; different binding; pillar arene

Journal Title: Organic letters
Year Published: 2020

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