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Polyynes to Polycycles: Domino Reactions Forming Polyfused Chalcogenophenes.

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Polyfused chalcogenophenes are prepared in one step through polyelectrophilic cyclization of polyynes using the ambiphilic reagent MeACl (A = S, Se, or Te). Up to four new rings have been… Click to show full abstract

Polyfused chalcogenophenes are prepared in one step through polyelectrophilic cyclization of polyynes using the ambiphilic reagent MeACl (A = S, Se, or Te). Up to four new rings have been generated under mild conditions, including thiophenes, selenophenes, and tellurophenes.

Keywords: polyynes polycycles; reactions forming; domino reactions; forming polyfused; polycycles domino; polyfused chalcogenophenes

Journal Title: Organic letters
Year Published: 2020

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