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A Photochemical Dehydrogenative Strategy for Direct and Regioselective Dimerization of BODIPY Dyes.

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By taking advantage of their intense visible-light absorptions, a photoinduced, AgI promoted oxidative dimerization of BODIPY dyes was developed to give structurally unprecedented α,α- and α,γ-linked dimers. In contrast to… Click to show full abstract

By taking advantage of their intense visible-light absorptions, a photoinduced, AgI promoted oxidative dimerization of BODIPY dyes was developed to give structurally unprecedented α,α- and α,γ-linked dimers. In contrast to classical oxidative aromatic coupling, this methodology does not need a strong oxidant and relies on the singlet electron transfer process between excited-state BODIPYs and an electron acceptor to generate BODIPY based radical species.

Keywords: strategy direct; bodipy dyes; dimerization bodipy; photochemical dehydrogenative; dehydrogenative strategy

Journal Title: Organic letters
Year Published: 2020

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