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Although many chiral molecules exhibiting circularly polarized luminescence (CPL) have been reported recently, few molecular design guidelines are known for increasing the dissymmetry factor for CPL (glum). We demonstrate that… Click to show full abstract
Although many chiral molecules exhibiting circularly polarized luminescence (CPL) have been reported recently, few molecular design guidelines are known for increasing the dissymmetry factor for CPL (glum). We demonstrate that a figure-eight-shaped molecule with D2 symmetry has excellent chiroptical properties (Φf = 0.08, |glum| = 1.5 × 10-2), which are attributed to the parallel arrangement of μ and m as well as a good |μ|/|m| ratio.
Keywords:
circularly polarized;
eight shaped;
polarized luminescence;
figure eight;
symmetry
Journal Title: Organic letters
Year Published: 2020
Link to full text (if available)
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Journal Title: Organic letters
Year Published: 2020
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!