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Herein, we report the synthesis and properties of a [6,6] hollow bilayer cylindrical nanoring (HBCNR) from a planar macrocycle via a Diels-Alder and Yamamoto coupling reaction. The fluorescence quantum yield… Click to show full abstract
Herein, we report the synthesis and properties of a [6,6] hollow bilayer cylindrical nanoring (HBCNR) from a planar macrocycle via a Diels-Alder and Yamamoto coupling reaction. The fluorescence quantum yield of HBCNR was determined to be ΦF = 52%, which is four times higher than its precursor. In addition, its hollow nanoring configuration was also simulated by theoretical studies, and the tension energy was estimated to be 47.1 kcal/mol.
Keywords:
cylindrical nanoring;
properties phenanthrene;
hollow bilayer;
bilayer cylindrical;
physical properties;
synthesis physical
Journal Title: Organic letters
Year Published: 2021
Link to full text (if available)
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Journal Title: Organic letters
Year Published: 2021
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!