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A powerful and environmentally friendly electrochemical manganese-promoted free radical selenylation reaction between boronic acids and diselenide reagents was established. This electrochemical protocol provides a practically applicable way to a series… Click to show full abstract
A powerful and environmentally friendly electrochemical manganese-promoted free radical selenylation reaction between boronic acids and diselenide reagents was established. This electrochemical protocol provides a practically applicable way to a series of valuable organoselenium compounds with the use of easy available materials. Mechanistic experiments implied that the seleno-radical formed via direct or indirect electrochemical oxidation of diselenide may be involved as a key species in this transformation.
Journal Title: Organic letters
Year Published: 2022
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