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Fe-Catalyzed Dicarbofunctionalization of Vinylarenes with Alkylsilyl Peroxides and β-Keto Carbonyl Substrates.

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The formation of two carbon-carbon bonds using vinylarenes with alkylsilyl peroxides and β-keto carbonyl substrates is effected by the presence of catalytic Fe(OTf)2 under mild reaction conditions. A variety of… Click to show full abstract

The formation of two carbon-carbon bonds using vinylarenes with alkylsilyl peroxides and β-keto carbonyl substrates is effected by the presence of catalytic Fe(OTf)2 under mild reaction conditions. A variety of vinylarenes with different substituents can be utilized in combination with several different alkylsilyl peroxides and β-keto carbonyl substrates.

Keywords: vinylarenes alkylsilyl; peroxides keto; alkylsilyl peroxides; keto carbonyl; carbonyl substrates

Journal Title: Organic letters
Year Published: 2022

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