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A catalytic glycosyl fluoride activation system using the GeCl2·dioxane-AgBF4 combination was developed, which involves a reversible activation of the anomeric C-F bond by a [Ge(II)-Cl]+ cation and a reversible chloride… Click to show full abstract
A catalytic glycosyl fluoride activation system using the GeCl2·dioxane-AgBF4 combination was developed, which involves a reversible activation of the anomeric C-F bond by a [Ge(II)-Cl]+ cation and a reversible chloride ion transfer between Ge(II) and glycosyl cations. This catalytic glycosylation system is easy to operate, proceeds at room temperature, and offers a broad scope of substrates.
Keywords:
glycosyl;
gecl2 dioxane;
activation;
dioxane agbf4
Journal Title: Organic letters
Year Published: 2022
Link to full text (if available)
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Journal Title: Organic letters
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!