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Photoinduced Silylation of N-Heteroarenes and Unsaturated Benzamides with Naphthalimide-Based Organic Photocatalysts.

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Described herein is the development of a general strategy for the silylation of N-heteroaromatics and unsaturated benzamides via the rational designing of an efficient organic photocatalyst. The process features operational… Click to show full abstract

Described herein is the development of a general strategy for the silylation of N-heteroaromatics and unsaturated benzamides via the rational designing of an efficient organic photocatalyst. The process features operational simplicity, mild reaction conditions, and the use of readily prepared naphthalimide (NI)-based organic photocatalysts. Notably, both inert trialkylhydrosilanes and arylhydrosilanes are well tolerated with this protocol.

Keywords: naphthalimide based; photoinduced silylation; organic photocatalysts; unsaturated benzamides; based organic

Journal Title: Organic letters
Year Published: 2022

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