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A novel N-rimmed PAH molecule containing a dipleiadiene core (TIDP) was designed and synthesized from indole, wherein a ZrCl4-promoted intramolecular C4-H homocoupling reaction of the indole moieties was the key… Click to show full abstract
A novel N-rimmed PAH molecule containing a dipleiadiene core (TIDP) was designed and synthesized from indole, wherein a ZrCl4-promoted intramolecular C4-H homocoupling reaction of the indole moieties was the key approach. TIDP exhibited a nearly full planar structure and antiaromaticity of the two embedded heptagonal rings. The extremely stable radical cation TIDP•+·PF6- was isolated quantitatively by oxidation with AgPF6.
Keywords:
via zirconium;
zirconium promoted;
intramolecular indolyl;
promoted intramolecular;
planar tetraindolodipleiadiene;
tetraindolodipleiadiene via
Journal Title: Organic letters
Year Published: 2022
Link to full text (if available)
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Journal Title: Organic letters
Year Published: 2022
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!