2-Naphthols 1 were found to react with aryl isothiocyanates 2 to provide 2-iminonaphtho-1,3-oxathioles 3 in the presence of DABCO as a catalyst. When elemental sulfur was used, moderate to good… Click to show full abstract
2-Naphthols 1 were found to react with aryl isothiocyanates 2 to provide 2-iminonaphtho-1,3-oxathioles 3 in the presence of DABCO as a catalyst. When elemental sulfur was used, moderate to good yields of 3 could be achieved from a nearly equimolar mixture of two starting materials 1 and 2. Products 3 could also be formed in the absence of sulfur or an external oxidant. In the latter case, an additional equivalent of 2 was found to act as a dehydrogenating agent.
Keywords:
catalyzed reaction;
reaction naphthols;
dabco catalyzed;
aryl isothiocyanates;
naphthols aryl;
iminonaphtho oxathioles
Journal Title: Organic letters
Year Published: 2022
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Journal Title: Organic letters
Year Published: 2022
Link to full text (if available)
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recommendations!