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A selective oxidative coupling reaction of a diamine containing both C- and N-NH2 was achieved using acidic potassium permanganate as the coupling reagent. The reaction conditions were optimized, and the… Click to show full abstract
A selective oxidative coupling reaction of a diamine containing both C- and N-NH2 was achieved using acidic potassium permanganate as the coupling reagent. The reaction conditions were optimized, and the reaction selectivity was illustrated by quantum calculations. Furthermore, the azo-coupled product was derivatized to four nitroamine energetic materials with excellent detonation performances.
Keywords:
site selective;
reaction;
coupling reaction;
reaction diamines;
oxidative coupling;
selective oxidative
Journal Title: Organic letters
Year Published: 2023
Link to full text (if available)
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Journal Title: Organic letters
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!