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Here we report catalytic asymmetric hydrophosphination of α,β-unsaturated carbonyl derivatives using a chiral Mn(I) complex as a catalyst. Through H–P bond activation, various phosphine-containing chiral products can be accessed via… Click to show full abstract
Here we report catalytic asymmetric hydrophosphination of α,β-unsaturated carbonyl derivatives using a chiral Mn(I) complex as a catalyst. Through H–P bond activation, various phosphine-containing chiral products can be accessed via hydrophosphination of various ketone-, ester-, and carboxamide-based Michael acceptors.
Keywords:
manganese catalyzed;
unsaturated carbonyl;
asymmetric hydrophosphination;
hydrophosphination;
carbonyl derivatives;
hydrophosphination unsaturated
Journal Title: Organic Letters
Year Published: 2023
Link to full text (if available)
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Journal Title: Organic Letters
Year Published: 2023
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!