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Nickel Catalyzed Cross-Coupling of Aryl and Alkenyl Triflates with Alkyl Thiols.

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We report a nickel catalyzed C-S cross-coupling of aryl and alkenyl triflates with alkyl thiols. A variety of the corresponding thioethers were synthesized using an air-stable nickel precatalyst under mild… Click to show full abstract

We report a nickel catalyzed C-S cross-coupling of aryl and alkenyl triflates with alkyl thiols. A variety of the corresponding thioethers were synthesized using an air-stable nickel precatalyst under mild reaction conditions with short reaction times. A broad substrate scope, including pharmaceutically relevant compounds, could be demonstrated.

Keywords: coupling aryl; alkenyl triflates; cross coupling; nickel catalyzed; aryl alkenyl; catalyzed cross

Journal Title: Organic letters
Year Published: 2023

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