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Highly Stereoselective Assembly of 1,2-cis-Arap Linkages.

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Highly stereoselective construction of 1,2-cis-Arap linkages has been achieved, which featured a broad range of alcoholic acceptors, including strong nucleophiles and complex bioactive molecules. This method was applied to a… Click to show full abstract

Highly stereoselective construction of 1,2-cis-Arap linkages has been achieved, which featured a broad range of alcoholic acceptors, including strong nucleophiles and complex bioactive molecules. This method was applied to a regioselective and orthogonal one-pot synthesis of a pentasaccharide, which was the structural motif of a side chain in type II arabinogalactan.

Keywords: cis arap; arap linkages; stereoselective assembly; highly stereoselective

Journal Title: Organic letters
Year Published: 2023

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