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Nickel-Catalyzed Isomerization of Homoallylic Alcohols.

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Nickel-catalyzed isomerizations of homoallylic alcohols and a bishomoallylic alcohol are presented. These isomerization reactions occur in the presence of a simple nickel catalyst that does not require addition of an… Click to show full abstract

Nickel-catalyzed isomerizations of homoallylic alcohols and a bishomoallylic alcohol are presented. These isomerization reactions occur in the presence of a simple nickel catalyst that does not require addition of an exogenous ligand. The corresponding ketone products are generated in ≤98% yield.

Keywords: nickel catalyzed; isomerization homoallylic; homoallylic alcohols; catalyzed isomerization

Journal Title: Organic letters
Year Published: 2023

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