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Catalytic and Enantioselective Diels-Alder Reactions of (E)-4-Oxopent-2-enoates.

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Novel oxazaborolidines activated by the strong acid triflimide or AlBr3 form cationic chiral catalysts. These are effective catalysts for highly regio- and enantioselective Diels-Alder reactions using substituted (E)-4-oxopent-2-enoates as dienophiles. Click to show full abstract

Novel oxazaborolidines activated by the strong acid triflimide or AlBr3 form cationic chiral catalysts. These are effective catalysts for highly regio- and enantioselective Diels-Alder reactions using substituted (E)-4-oxopent-2-enoates as dienophiles.

Keywords: catalytic enantioselective; diels alder; reactions oxopent; oxopent enoates; enantioselective diels; alder reactions

Journal Title: Organic letters
Year Published: 2017

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