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Direct Synthesis of Large-Scale Ortho-Iodinated Perylene Diimides: Key Precursors for Functional Dyes.

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A highly regioselective tetra-ortho-iodination reaction of perylene diimides (PDIs) has been developed, which could be conducted on a multigram scale (>10 g), featuring a column chromatography-free workup and purification. The… Click to show full abstract

A highly regioselective tetra-ortho-iodination reaction of perylene diimides (PDIs) has been developed, which could be conducted on a multigram scale (>10 g), featuring a column chromatography-free workup and purification. The ortho-iodinated-PDIs serve as key intermediates for the preparation of a variety of ortho-functionalized PDIs and PDI-based conjugated polymers.

Keywords: perylene diimides; synthesis large; direct synthesis; ortho iodinated

Journal Title: Organic letters
Year Published: 2017

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