Photo by bermixstudio from unsplash
Hydrosilylation of various sulfur-containing olefins with (RO)3SiH has been achieved using iridium catalysts [IrX(cod)]2 (X = Cl, SPh). The catalysis is applicable to the chemoselective hydrosilylation of thioacetate, which enables… Click to show full abstract
Hydrosilylation of various sulfur-containing olefins with (RO)3SiH has been achieved using iridium catalysts [IrX(cod)]2 (X = Cl, SPh). The catalysis is applicable to the chemoselective hydrosilylation of thioacetate, which enables the preparation of an industrially important silane coupling agent.
Keywords:
catalyzed hydrosilylation;
iridium catalyzed;
containing olefins;
sulfur containing;
hydrosilylation
Journal Title: Organic letters
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!
Journal Title: Organic letters
Year Published: 2018
Link to full text (if available)
Share on Social Media: Sign Up to like & get
recommendations!