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Oxidative Dehomologation of Aldehydes with Oxygen as a Terminal Oxidant.

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A mild, efficient protocol for oxidative cleavage of C-C bonds in aldehydes has been developed that employs alkali metal hydrides as reagents and oxygen from air as a terminal oxidant.… Click to show full abstract

A mild, efficient protocol for oxidative cleavage of C-C bonds in aldehydes has been developed that employs alkali metal hydrides as reagents and oxygen from air as a terminal oxidant. The method is applicable to a broad substrate range.

Keywords: oxidative dehomologation; aldehydes oxygen; dehomologation aldehydes; oxygen terminal; terminal oxidant

Journal Title: Organic letters
Year Published: 2017

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