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Cascade Dehydrogenative Hydroboration for the Synthesis of Azaborabenzofulvenes.

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Tandem dehydrogenative hydroboration has been established to be highly effective in the synthesis of BN isosteres of benzofulvene and derivatives. The scope of this synthetic method is applicable to a… Click to show full abstract

Tandem dehydrogenative hydroboration has been established to be highly effective in the synthesis of BN isosteres of benzofulvene and derivatives. The scope of this synthetic method is applicable to a variety of substrates. Spectroscopic and computational studies indicate that the new azaborabenzofulvenes have similar electronic properties as their carbonaceous analogues.

Keywords: hydroboration synthesis; dehydrogenative hydroboration; cascade dehydrogenative; synthesis azaborabenzofulvenes; hydroboration

Journal Title: Organic letters
Year Published: 2018

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