Tandem dehydrogenative hydroboration has been established to be highly effective in the synthesis of BN isosteres of benzofulvene and derivatives. The scope of this synthetic method is applicable to a… Click to show full abstract
Tandem dehydrogenative hydroboration has been established to be highly effective in the synthesis of BN isosteres of benzofulvene and derivatives. The scope of this synthetic method is applicable to a variety of substrates. Spectroscopic and computational studies indicate that the new azaborabenzofulvenes have similar electronic properties as their carbonaceous analogues.
               
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