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Collimonins A-D, Unstable Polyynes with Antifungal or Pigmentation Activities from the Fungus-Feeding Bacterium Collimonas fungivorans Ter331.

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The isolation and structure elucidation of collimonins A-D (1-4) from the fungus-feeding bacterium Collimonas fungivorans Ter331 are reported. Collimonins are new derivatives of polyoxygenated hexadecanoic acid, including an ene-triyne moiety.… Click to show full abstract

The isolation and structure elucidation of collimonins A-D (1-4) from the fungus-feeding bacterium Collimonas fungivorans Ter331 are reported. Collimonins are new derivatives of polyoxygenated hexadecanoic acid, including an ene-triyne moiety. Their absolute configurations were fully determined by combining spectroscopic, chemical, and crystalline sponge methods. Collimonins showed antifungal or pigmentation activities against the fungus Aspergillus niger ATCC 9029.

Keywords: fungus feeding; fungivorans ter331; feeding bacterium; antifungal pigmentation; collimonas fungivorans; bacterium collimonas

Journal Title: Organic letters
Year Published: 2018

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