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Synthesis of o-Arylenediamines through Elemental Sulfur-Promoted Aerobic Dehydrogenative Aromatization of Cyclohexanones with Arylamines.

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Herein, the first elemental sulfur-promoted aerobic dehydrogenative aromatization of cyclohexanones is described that provides novel access to synthetically useful o-arylenediamines. This protocol complements previous palladium- and iodine-catalyzed diarylamine formation from… Click to show full abstract

Herein, the first elemental sulfur-promoted aerobic dehydrogenative aromatization of cyclohexanones is described that provides novel access to synthetically useful o-arylenediamines. This protocol complements previous palladium- and iodine-catalyzed diarylamine formation from cyclohexanones and anilines.

Keywords: promoted aerobic; sulfur promoted; aromatization cyclohexanones; dehydrogenative aromatization; aerobic dehydrogenative; elemental sulfur

Journal Title: Organic letters
Year Published: 2018

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