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Plasmonic Effect with Tailored Au@TiO2 Nanorods in Photoanode for Quantum Dot Sensitized Solar Cells

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Quantum dot sensitized solar cells (QDSCs) are recognized as one of the most promising candidates in converting solar energy into electric energy. The ideal solar cells should meet the demands… Click to show full abstract

Quantum dot sensitized solar cells (QDSCs) are recognized as one of the most promising candidates in converting solar energy into electric energy. The ideal solar cells should meet the demands including high light-harvesting capacity and charge transfer rate. However, the current power conversion efficiency of QDSCs remains low, due to insufficient light absorption of the photoanode and the sluggish charge extraction rate from quantum dots to TiO2. In the device, TiO2 performs the function of loading quantum dots and transmitting photogenerated electrons; thus, the TiO2 films should be carefully designed and constructed. In this work, the as-prepared Au nanorods coated with TiO2 are incorporated into TiO2 film electrode. Benefiting from the plasmonic effect of Au nanorods, the resulted photoanodes exhibit an enhanced light-scattering effect, consequently improving the light-harvesting efficiency of the photoanode. Meanwhile, photoelectric characterization reveals that the formed interface of Au nanorods/T...

Keywords: solar cells; quantum dot; sensitized solar; dot sensitized; plasmonic effect; effect

Journal Title: ACS Applied Energy Materials
Year Published: 2019

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