A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials… Click to show full abstract
A manganese-based metal-organic framework with dipyrazole ligands has been metalated with atomically dispersed Rh and Co species and used as a catalyst for the hydroformylation of styrene. The Rh-based materials exhibited excellent conversion at 80 °C with complete chemoselectivity, high selectivity for the branched aldehyde, high recyclability, and negligible metal leaching.
Keywords:
postsynthetic metalated;
atomically dispersed;
hydroformylation;
mofs atomically;
dispersed catalysts;
metalated mofs
Journal Title: ACS applied materials & interfaces
Year Published: 2020
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Journal Title: ACS applied materials & interfaces
Year Published: 2020
Link to full text (if available)
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recommendations!