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Slippery Antifouling Polysiloxane-Polyurea Surfaces with Matrix Self-Healing and Lubricant Self-Replenishing.

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The inferior mechanical properties and the difficulty in repairing damaged substrates and lubricant films of slippery liquid-infused porous surfaces significantly hampered their practical applications. To solve this problem, we fabricated… Click to show full abstract

The inferior mechanical properties and the difficulty in repairing damaged substrates and lubricant films of slippery liquid-infused porous surfaces significantly hampered their practical applications. To solve this problem, we fabricated a polysiloxane-polyurea slippery elastomer with lubricant self-replenishing and matrix self-healing properties by encapsulating silicone oil into the thermoplastic elastomers. By optimizing the chemical compositions and molecular interactions, the obtained slippery elastomer exhibits unique mechanical properties with a maximum breaking strength of 0.12 MPa, elongation of 1600%, and self-healing efficiency of 98%. Moreover, the lubricant stored in the capsule of the slippery elastomer can be controlled released under mechanical stimulation, further realizing surfaces' self-lubricating and liquid manipulation switching between slippery and pinning states. Furthermore, the textile-reinforced slippery elastomer with superior mechanical strength also exhibited liquid repellency, anti-biofouling, and drag reduction properties. Therefore, this textile-reinforced omniphobic surface with high mechanical property, matrix self-healing, and lubricant self-replenishing property shows a broad application prospect in surface protection, underwater antifouling, and drag reduction.

Keywords: slippery; lubricant self; self replenishing; self; matrix self; self healing

Journal Title: ACS applied materials & interfaces
Year Published: 2021

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