Ice accretion can adversely impact many engineering structures in commercial and residential sectors. Although there are many reports of low-ice-adhesion-strength materials, a scalable and durable deicing solution remains elusive, as… Click to show full abstract
Ice accretion can adversely impact many engineering structures in commercial and residential sectors. Although there are many reports of low-ice-adhesion-strength materials, a scalable and durable deicing solution remains elusive, as ice detachment is dominated by interfacial toughness for large interfaces. In this work, durable metallic coatings based on Al-rich quasicrystalline alloys were prepared and applied on aluminum substrates using high-velocity oxyfuel thermal spray. X-ray diffraction patterns confirmed the quasicrystalline phases of the coating, and its large-scale deicing capability was studied by evaluating the coating's ice detachment mechanics using long lengths of ice. A toughness-controlled regime of interfacial fracture was observed for ice lengths longer than ∼2 cm, and a low shear strength of ∼30 kPa was achieved for a 20 cm ice length. The metallic coatings exhibited excellent ice repellency even after being abraded, scratched, heated, UV-irradiated, and exposed to chemical contaminations, demonstrating promising durability for real-world, large-scale ice removal.
               
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