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Mesoporous Solid and Yolk-Shell Titania Microspheres as Touchless Colorimetric Sensors with High Responsivity and Ultrashort Response Times.

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Touchless user interfaces offer an attractive pathway toward hygienic, remote, and interactive control over devices. Exploiting the humidity generated from fingers or human speech is a viable avenue for realizing… Click to show full abstract

Touchless user interfaces offer an attractive pathway toward hygienic, remote, and interactive control over devices. Exploiting the humidity generated from fingers or human speech is a viable avenue for realizing such technology. Herein, titania microspheres including solid and yolk-shell structures with varying microstructural characteristics were demonstrated as high-performance, ultrafast, and stable optical humidity sensors aimed for touchless control. When water molecules enter the microporous network of the microspheres, the effective refractive index of the microsphere increases, causing a detectable change in the light scattering behavior. The microstructural properties of the microspheres, namely, the pore characteristics, crystallinity, and particle size, were examined in relation to the humidity-sensing performance, establishing optimum structural conditions for realizing humidity-responsive wavelength shifts above 100 nm, near full-scale relative humidity (RH) responsivity, ultrashort response times below 30 ms, and prolonged lifetimes. These optimized microspheres were used to demonstrate a colorimetric touchless sensor that responds to humidity from a finger and a microcontroller-based detector that translates the moisture pattern from human speech to electrical signals in real time. These results provide practical strategies for enabling humidity-based touchless user interfaces.

Keywords: titania microspheres; solid yolk; responsivity ultrashort; ultrashort response; humidity; yolk shell

Journal Title: ACS applied materials & interfaces
Year Published: 2021

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