LAUSR

Energy density in nonaqueous redox flow batteries (RFBs) is often limited by the modest solubility of the redox-active organic molecules (ROMs). In addition, the lack of a separator that prevents ROMs from crossing between anolyte and catholyte solutions necessitates the use of 1:1 mixtures of two ROMs in both the anolyte and catholyte solutions in symmetric RFBs, further limiting concentrations. We show that permanently cationic oligomers of viologen, tris(dialkylamino)cyclopropenium, and phenothiazine molecules have high solubility in acetonitrile and cross over an anion exchange membrane at slow to undetectable rates, enabling the creation of asymmetric RFBs with low crossover. No added supporting electrolyte is necessary, with only the PF6- counteranions of the ROMs crossing the membrane during charge/discharge. An oligomeric viologen + oligomeric cyclopropenium RFB at 1.0 M (redox equivalents) has a voltage of 1.66 V and a theoretical energy density of 22.2 Wh/L, one of the highest reported for nonaqueous RFBs.