LAUSR

Flexible electrochromic devices (FECDs) have been regarded as an ideal stratagem for wearable displays. However, it remains a great challenge to achieve long-term stability for high-performance FECDs due to their severe electrolyte deformation/leakage under repeated bending. Herein, inspired by the rough and fluffy microstructure of cobwebs, we prepared a porous polylactic acid (PLA) network through electrospinning and nonsolvent-induced phase separation. This loosely interlaced PLA network can be well infiltrated by electrolytes and exhibits extraordinarily high transparency; in addition, its surface contains numerous tiny holes to effectively load electrolytes to mitigate deformation. Furthermore, we also introduced silver nanowires (AgNWs) as the supporting network to load and connect electrochromic materials. After assembling them with graphene (GR) electrodes, a wearable FECD with a quintuple network structure (two GR networks, two AgNW networks, and one PLA network) was successfully prepared. The resulting FECD can realize high optical modulation (more than 70%), excellent cyclic stability (retain 95% after 1000 cycles), and innovative bending resistance (retain 84.8% after 6000 bending cycles). This work not only solves the long-lasting challenge of developing FECD with high optical modulation and bending resistances but also provides an energetic paradigm for diverse soft electronics used in harsh environments.