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A Nontoxic NFM Solvent for High-Efficiency Perovskite Solar Cells with a Widened Processing Window.

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With the steady industrialization process of the perovskite solar cells (PSCs), the toxicity of the used solvents has become a pivotal issue that needs to be addressed. Especially, the usage… Click to show full abstract

With the steady industrialization process of the perovskite solar cells (PSCs), the toxicity of the used solvents has become a pivotal issue that needs to be addressed. Especially, the usage of N,N-dimethylformamide (DMF) solvent would pose serious environmental and health concerns. Herein, we have reported a nontoxic solvent N-formylmorpholine (NFM) to replace the toxic DMF and have achieved a higher PCE of 22.78% compared to 21.97% when DMF was adopted. Moreover, with NFM, a widened antisolvent processing window was observed, facilitating the fabrication of PSCs with high reproducibility. This solvent engineering strategy offers an important solution to prepare eco-friendly, efficient, and stable perovskite solar cells.

Keywords: solar cells; solvent; nontoxic nfm; processing window; perovskite solar

Journal Title: ACS applied materials & interfaces
Year Published: 2022

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