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Post-synthetic Fully π-Conjugated Three-Dimensional Covalent Organic Frameworks for High-Performance Lithium Storage.

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A fully π-conjugated nitrogen-rich three-dimensional covalent organic framework (PYTRI-COF-2) containing both pyrazine and triazine units was prepared through a post-synthetic strategy. The imine linkages in the pre-prepared PYTRI-COF-1 were converted… Click to show full abstract

A fully π-conjugated nitrogen-rich three-dimensional covalent organic framework (PYTRI-COF-2) containing both pyrazine and triazine units was prepared through a post-synthetic strategy. The imine linkages in the pre-prepared PYTRI-COF-1 were converted into heterocyclic quinoline by the Povarov reaction. The obtained PYTRI-COF-2 displayed high Li-ion storage capacity and excellent cycling stability when it was used as the lithium (Li)-ion battery electrode.

Keywords: dimensional covalent; post synthetic; three dimensional; covalent organic; fully conjugated

Journal Title: ACS applied materials & interfaces
Year Published: 2022

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